[Isotope-prod] Gallium extraction before chemical processing
Pavel Degtiarenko
pavel at jlab.org
Sat May 26 22:34:37 EDT 2018
Hi All,
Found an interesting paper discussing Ga purification process via
electrolysis, using the GaCl4 electrolyte. They claim they can do
gallium purification to extremely high levels in one run, with
productivity of 1 kg of pure metal per day. That would mean few hours
for our 100-200 g targets. I guess it can be accelerated if needed,
either by design, or by parallel runs. The idea would be to run the
electrolyzer before the chemical separation, return, say, 99% of pure
gallium ready for the next irradiation right away, and then chemically
separate Cu-67 from the residuals. That would help increase Cu-67
concentration and make the amount of material for chemical separation
small, to avoid known difficulties of working with large volumes.
Best regards,
Pavel
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